I have also had that happen with sinew. I think what happens is that the glue dries/cures before the skin dries completely, not giving the moisture anywhere to go. make sure your skins are pliable but not dripping when you put the glue on. I soak them for 10 minutes or so then squeeze them out with a towel. But think about this, because copperhead skins are thinner, you may just be able to see the mold easier. for all I know, the same thing could be happening under other skins, but you cant see it because they are darker or thicker.