Never used a heat gun to straighten bamboo or cane, only a propane torch. Node areas require more of a spot heating which a torch easily provides. Like Jimmi, I'll hit the nodes with sandpaper before straightening, then a rough straightening of the nodes as needed, and then proceed to straighten the inner nodes. Then back to the nodes again. Repeat as needed.
To make the straightening process easier, and I'll not seen this mentioned before, there are only two planes to straighten on cane, bamboo, dowelled shafts and some hardwood shoots. For cane and boo, you need only to straighten the leaf scar side, and then rotate the shaft 1/4 turn and straighten it's side. So you only have to two sides to straighten here, instead of having to constantly rotating the shaft to locate it's crooks.
I made up a hardwood grooved straightening block to help with the process. Here's a pic...…...Art