I've read that sapwood doesn't differ from heartwood when it comes to primary components of cell wall (cellulose, hemicellulose, lignin, glucomannan, xylan). Cellulose microfibril angle also doesn't change. The observed difference in properties is therefore attributed to extractives deposited during the transition from sapwood to heartwood. Primarily polyphenols and flavonoids. These compounds are thought to interact with the cell wall and change its properties.
A dead tree shouldn't produce/deposit these compounds, sapwood should remain in place after it's dead. Unless sapwood transitions to heartwood in its entirety shortly before the tree dies (or during cell death!) we should be able to see it.
Now, any method introducing similar compounds during heat-treatment should stand to reason if the properties of heartwood are indeed due to extractives. Maelming and similar techniques might be effective. I wonder if those " revolutionary™, moisture proof fire dancer™" bows don't use something similar.