Yes it is the total thickness that determines draw weight not how much there is of each layer. A bow with thicker horn will take a little less set therefore draw weight will be slightly higher but no it is the total thickness that matters.
When Adam mentions adding more sinew I think he means proportionately more sinew rather than adding 'extra' sinew. The 100 grams advise is what to go with here. 100g will probably mean you end up with 2.5 - 3mm sinew over the center of the sal.
I only used around 70g on this particular bow and horn of around 3mm in the main bending section. If I remember right these horns were recovered from an older failed bow hence the limited thickness.
This bow is around 32mm wide in the sal.
I would advise moving the thinnest section out to 35cm even if it is slightly around the bend. If your thinnest spot is at 30cm then the sal will be over strained. Better to have the thinnest spot even out to 37.5cm from the handle to lower the strain a little further.
One of the most important steps of the whole process is making sure the core is perfectly sized. Make sure you do not touch it with bare hands once it is prepared. A lot of hornbows fail because of broken cores where the sinew/wood bond isn't perfect (don't ask me how I know that one….haha).
Heat the whole core and use 5% glue for the first few coats. Very light sanding (240grit) inbetween if any fibers raise. Then you can increase the thickness of glue a little. Make sure it is glossy everywhere.
Good luck