OK, I have a couple of thoughts, even though I have zero experience with a thumb release, so I can't help with the first part of your post. It seems like if your shoulder hurts, you should focus more on using your back muscles (lift your bow like doing a curl with a barbell and you will feel the right ones). Pushing towards the target with the bow arm always seems to help me - it should help avoid collapsing and give a cleaner release. Hopefully this response will either help, or irritate someone who knows more, so they will chime in...