If you are interested in ironworking by Plains tribes, I recommend a book by a guy I know, James A. Hanson of the Museum of the Fur Trade. The title is "Metal Weapons, Tools, and Ornaments of the Teton Dakota Indians " He has handled thousands of artifacts from pre-contact to contemporary times.
He spoke at a historical conference a few years ago and he indicated he had seen several hundred axe heads from the fur trade era and every last one of 'em had chisel marks on the flat sides and poll. An axe could be sunk in a downed tree trunk or stump and used as a portable anvil! In lists of trade goods from various trading posts and traveling traders, hammers, cold chisels and files were common items. I doubt they were for dentistry.
Items commonly traded or scavanged for turning out knives and arrowheads include barrel hoops, wagon wheel iron, buckets, pails, cook pots, spoons, and so on. They may not have done much in the way of classic blacksmithing with forges and welding, but they were absolute whizzes at stock reduction and stock removal.
And yes, there were roughed out trade point arrowheads traded in the fur trade times as well.